The Amazing Spider-Man Vol. 2 (1998-2013) #572

Plot

Peter discovers that the illegal immigrants have been undergoing medical experiments at Oscorp. Norman extracts material out of Gargan and runs the substance through the captured Freak, thus producing a strong new poison. Bullseye and Thunderbolt agents attack Spider-Man and end up blowing up Harry's coffee shop during the battle. Spidey quickly discovers how he is being tracked and turns the tables on Bullseye. Anti-Venom shows up to help Spider-Man track down Osborn. Norman, now in full Goblin regalia, provides Gargan with a new Scorpion costume complete with the new poison.