The Amazing Spider-Man Vol. 2 (1998-2013) #597

Plot

Thanks to a "Venom" suit developed by Reed Richards, Spider-Man has secretly replaced Mac Gargan on the Dark Avengers; Norman reveals to his team that their newest member will be his son Harry dressed in Captain America like armor and called American Son; Harry finds Lily in Avengers Tower and promises to cure her of the goblin serum in her blood that turns her into Malice; Daken sniffs out the fact that Peter is impersonating Mac's version of Spider-Man and attacks; Spidey wins the battle but is ratted out by Harry who tells his dad that the Spider-Man in front of him is the real deal; Hawkeye shoots Spidey in the legs and Norman pulls out a gun and shoots him in the face.